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Ha paax pyoc HMATH AT PATOB PAPAOTA PMEHEHE PACTBOPTE AETOH MET-TPET-TOB P POBOCTBA HETHX MACE APAHOB Ceaoc 05.17.07 - X exoo o ceax poyo ABTOPEEPAT ccepa a cocae yeo cee aaa execx ay a - 2002 Paoa oea a aepe exoo e aa coo ocyapceoo eoo execoo yepcea.

Hay pyooe oop execx ay, poeccop Oo ae eoe.

Oae ooe: oop execx ay, oe a a apo;

aa execx ay, a op epo.

Beya opaa ocyapceoe yapoe pepe "cy eexepepao" aa ccepa cococ 27 eap 2002 oa 14 aco a acea ccepaooo coea 212.289.03 p co ocyapceo eo execo yepcee o apecy:

450062, Pecya aopoca, . a, y. ocoao, 1.

C ccepae oo oaoc oee coo ocyapceoo eoo execoo yepcea.

Aopeepa paoca 27 op 2002 oa.

e cepeap ccepaooo coea Aye ..

2 ATAHOCT TEM opeoc epax acax ae cpae yeaec oa o. p x pooce o ocox ec poecc eapaa pcaae epx yeoopoo paex pacopex.

poecc eapaa paao oeaca ae c aoee co opooco cxeax copeex acooo. Xapaepo ocoeoc x poecco c coe epeece apa a peeepa pacope oxaee cpeo cyce o x eepayp.

Cpe oocex aopo, x a exo-ooece oaae poecco eapaa oeaca, o ocox ec ppoa coca peeoo pacope.

pee poeccax eapaa oeaca pacope opeee oc oxaaeoo pacopa cp, a, ceoaeo, yco pcaa epx yeoopoo, eepayp e eapaa eepayp pe peeepa, o oaae cyeceoe e a yee epoapa. Haoee pacpocpae pacope poeccax eapaa oeaca c, epy oepe, eoapoaece: aeo-oyo eeo (M)-oyo. p o a ocyc pooca M Pocc, o acoeo pee eo ocaa ocyecec -a pyea. B c c cee apa poeccax eapaa oeaca c cooae ox cocao pacopee oeeceoo pooca ec eca ayao aae.

ccepaoa paoa oea paax: eoo aaa-apa o eaecoy ay HP HT a 2000-2001 . Mcepca opaoa P; eyoco ayo-execo popa oecoe peee poe papao, pacopa yoo epepao e aa (1999-2000 .).

E PAOT cceoae oooc cooa epe-yooo pa (MT) cec c aeoo aeo-oyoo poeccax eapaa paao oeaca ae.

HAHA HOBHA 1. peoe poecco eapaa paao oeaca ae pacope aeo-MT c ooopaye oao.

2. caoeo, o p coepa o pacopee aeo-MT = =30:70 (ec aee % oe.) oece oee 0,5% aeo yeaec xo eapapoaoo aca yeaec coepae aca ae.

3. caoeo, o eee ooopayx oao pacope aeo-MT cococye yee copoc pa ooe pe pacope c oee co coepae o. o eoc cceoae ooopaye oa pacoaac ceye oceoaeoc: NaOH > NaCl > KCl.

4. caoeo, o eepaypa aca ox pacopo ooopayx oao pacopee opeee eepayp aao x pee.

PATECA EHHOCT 1. caoe oae coca pacopee aeo-MT = =(30..40)-(60..70) aeo-MT-oyo = 32:48:20, oope oecea aye exo-ooece oaae poecca eapaa.

2. peoe aece ooopayx oao eo NaOH, co NaCl, ooe poo poecc eapaa paao oeaca ae c ooe pacopee.

3. coepecoaa ccea peeepa pacope poecce eapaa c cooae xpeoo eooea, o ooo c exooeco cxe oee peeepa ooy ooy, p eooea opyo xoo ccee peeepa.

4. Papaoaa popaa poee oo-poeoo poea a ycaoe eapaa paao c cooae pacope aeo-MT.

APOA PAOT Ocoe ooe ccepaoo pao oaac ocyac a ceyx ayx oepex:

II opecc eeaopoeo Pocc Heeepepaoa eex poe epce (. a, 2000 .); Bopo Meyapo coy Haya exoo yeoopox cepcx cce; III opecc eeaopoeo Pocc Heeepepaoa eex poe epce (. a, .); XIV Meyapoa ayo-execa oepe Xece pea, peae poecc aooao x (PEATB-2001).

A Coepae ccepa opaeo oyoax paoax (3 ca, 10 eco oao, 1 cpaooe ocoe).

CTPTPA OEM CCEPTA ccepa coco ee, a, ox oo, cca cooao epayp, aeo 169 aeoa. Paoa oea a 161 cpae aocoo eca, coep 20 pcyo, 29 a 2 poe.

COEPAHE PAOT BO BBEEH oocoaa ayaoc pao, eoxooc ce apa poeccax eapaa paao oeaca ae c cooae pacopee aeo-MT aeo-MT-oyo.

B EPBO ABE pee oop ayo-execo epayp o ee ccepa. opao cyaa ace aex, aax, exaax peyc oacae aca, oopx yae cooae yeoopo pao ppo. poecc eapaa cy x p cy oye eapapoax ace c eepaypo aca o 10 o 600C.

Coae poecca oeepaypo eapaa, aa c aopaopo popao, ca a oo ycaoe oceyeo poepoa, pae ooeey coecoy pyy BH H poeoy cyy poeeao. oo a pae poecco oeaca ae ec py poH.

oaao, o poecc eapaa paao oeaca ae ocoo coepecyc. ae, peee epo ae, oo copypoa e aa cceoa.

BO BTOPO ABE oca oe eo cceoa.

pee eo eapaa paao oeaca ae, oeoa pacopee.

TPET ABA ocea opy oaoo cocaa pacope poecca eapaa paao oeaca ae. B oeeceo epaype cooee o oooc pee MT ae oyoa p eapaa paao oeaca ae ooc 1988 . Ceo MT Pocc ec oooa poyo, paaae a eeepepaaax eexecx pepx o T 38.103704-90. paa xapaepca cceoax pacopee peea a. 1.

Taa paa xapaepca pacopee Haeoa oaaee Pacope aeo MT M oyo 1.ooc p 200C, /3 790,8 740,5 805,0 866,2.Boc ea. p 200C, 2/c 0,41 0,49 0,52 0,3.Teepaypa e, 0C 56,5 55,2 79,6 110,4.Teepaypa aca, 0C -95,5 -108,6 -86,4 -94,5.Pacopoc o pacopex 1,5 9,39 0,034+ p 200C, /100 6.Pacopoc pacope oe 4,8 22,6 0,037+ p 200C, /100 7.Coca aeopoo cec: e e 89:11 80,4:19,pacope:oa, % acc. opaye opaye 8.aee acex apo p 300C, 37,59 44,63 16,14 4,a 9.o oe, D 2,72 1,36 2,76 0,10.Cooc (a 01.06.2002), py./ 9600 11532 36270 o o apaepa MT oeae peoa, pee pacope eapaa paao oeaca ae.

MT epec co, oaae o eepaypo e.

Boc MT 1,5 paa e oc oyoa. Opaae a ce ae o, o cooc peaaeoo pacope aeo-MT oee e a paa e peeoo pacope M-oyo.

paoaoo cooa MT cocae pacope eapaa paao oeaca ae a cceoaa pacopoc apaa ap T MT pyx ecx pacopex (pc. 1). opeee eepayp pacopoc cx eapapoax ace cecx M-oyo aeoMT (a. 2).

oyex ax o o, ecop a ooceo coy opoc, MT oaae coo pacope cocooc. o coe pacope cocooc o ooe ep yeoopoa MT aae poeyooe ooee ey oyoo M.

5 10 15 20 25 30 35 40 45 50 Teepaypa, 0C aeo M aeo-MT (40:60) M-oyo (60:40) aeo-MT (30:70) MT oyo Pc. 1. Pacopoc apaa (Ta+520C) pax pacopex Taa Teepayp pacopoc eapapoax ace e.aco II .. e.aco III.. e.aco IV ..

Pacope 300-4000C, 350-4200C, 420-5000C, 50=5,832/c, 100=5,22/c, 50=7,562/c, c c c t= -550C t= -210C t= -170C Aeo 35,4 52 M -16 -8,5 1,MT e -65 e -65 e -M:oyo 80:20 -60 -50 -M:oyo 60:40 e -65 e -65 - apa, /100 pacope acoc eepayp pacopoc eapapoax ace o cocaa pacope aeo-MT pecaea a pc. 2.

-----0 20 40 60 80 Coepae MT pacopee MT-aeo, % II aca pa III aca pa IV aca pa Pc. 2. acoc eepayp pacopoc eapapoax ace o cocaa pacope aeo-MT Taa Ocoe oaae aeca paao Haeoa oaaee Paa II .p. III .p. IV .p.

1 2 3 1.ooc p 200C, /3 852,0 867,0 876,2.Boc eaeca, 2/c p 500C 7,6 16,7 30,p 1000C 3,2 4,65 7,3.Teepaypa c apo e, 0C 152,0 186,0 201,4.Teepaypa ae, 0C 20,0 32,0 41,5.pao coca, 0C t 272 318 t10 315 369 t50 358 394 t90 392 420 t98 418 468 6.pyoo yeoopo coca, % acc.

- apao-aeoe 78,0 66,0 60,- apoaece 21,5 33,3 39,- co 0,5 0,7 0,Teepaypa pacopoc coo e.aca, C C cooae pacopee M-oyo (60:40) aeo-MT (40:60) aopaopx ycox poee eapaa cx paao oeacae ae. aeco paao pecaeo a. 3. Peya eapaa pecae a. 4.

Taa Peya eapaa cx paao Pacope Haeoa oaaee M-oyo aeo-MT II III IV II III IV 1.Coooee pacope:cpe (o ecy) I cye 4:1 3,2:1 3,5:1 4:1 3,2:1 3,5:II cye 5:1 3,5:1 4:1 5:1 3,5:1 4:2.Pacope a poy I 100,0 100,0 100,0 100,0 100,0 100,cye, % a cpe 3.Teepaypa pa I cye -52 -23 -23 -52 -23 -4.Bxo e.aca, % acc. 72,0 80,0 78,4 71,5 79,6 76,5.Teepaypa aca e.aca, 0C -45 -15 -15 -45 -15 -6.Coepae aca ae, % acc. 30,0 25,6 28,8 31,5 26,4 30,7.Copoc pa, 3/2 o 0,62 0,54 0,65 1,09 0,68 0,cp Copoc pa cpeo cyce p eapaa paao opaea a pc. 3.

1,0,0,0,0,IV pa III pa II pa M-oyo aeo-MT Pc. 3. Copoc pa paao c pacope M-oyo (60:40) aeo-MT (40:60) Copoc pa, / aee poee cepe o oeaca ae.

oaae aeca ae pecae a. 5.

Taa oaae aeca oeacaex ae oaae III .p. IV . p.

ooc p 200C, /3 846,5 852,Boc p 1000C, 2/c 4,20 5,Teepaypa ae, 0C 48 Teepaypa c opo e, 0C 193 Coepae aca, % 24,0 28,Coepae cep, % 0,40 0,Moeypa acca 370 oaae peoe p 700C 1,4358 1,pao coca o oaoy, 0C t 335 t10 387 t50 406 t90 418 t 460 pyoo yeoopo coca, % apao-aeoe 91,0 71,apoaece 8,5 26,co 0,5 2,Peya oeaca ae pecae a. 6.

Taa Peya oeaca ae Haeoa oaaee Pacope M-oyo aeo-MT a III.., a IV.., a III.., a IV.., t=+490C t=+560C t=+490C t=+560C Coooee pacope:cpe a epo cye pa (ec.) 3,8:1 4:1 3,8:1 4:Teepaypa pa - epa cye -5 -3 -5 -- opa cye -3 -2 -3 --pe cye 0 0 0 Bxo apaa, % acc. 56,0 56,0 58,0 60,Coepae aca apae, % acc.

1,9 2,1 2,2 2,Teepaypa ae, 0C 52,0 57 51,0 pooeoc pa, c 64,0 60,0 60,0 56,pooeoc pa cpeo cyce p oeaca ae opaea a pc. 4.

III pa IV pa M-oyo aeo-MT Pc. 4. pooeoc pa ae c pacope M-oyo (60:40) aeo-MT (40:60) oyex ax o, o p cooa aece pacope aeo-MT poeccax eapaa paao copoc pa yeaec a 20-70%. B poecce oeaca ae pooeoc pa yeaec a 6-7%, a xo apaa a 2-4%.

Ta opao, cceye pacope aeo-MT e ycyae peeoy pacope M-oyo.

B ETBEPTO ABE paccopeo e o a poecc eapaa eo ocy pacope.

O eocao pacope aeo-MT ec oee coa pacopoc e o o cpae c coye pacopee M-oyo.

B c c cceoa pacopoc o pacopee aeoMT (30:70) oo pacope oe. cpaox ax eco, o aeo oa ao pacop x coooex, a MT pacope p eepaype 200C ooo 1,5% o oa ooo 4,8% MT.

Opa cepeo ooc p 250C cey opao:

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