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caoeo, o copoc pea xo poyo aeo cee ac o coooe peaeo, eepayp pooeoc pea (c. pc. 4).

a o pc. 4. aoee oa yco poee cea a epo ca ec eepaypa 100C, pe pea 2 aca, coooee 2,6--pe-yeo : cepoyepo, pa 1 : 2.

Bpe pea, Pc. 4. acoc oepc N,N-e-(3,5--pe-y-4poce)-aa xoa S-(3,5--pe-y-4-poce)oapaaa o pooeoc pea pe: 1,1' oepc, xo p eepaype 60C 2,2' - oepc, xo p eepaype 80C 3,3' - oepc, xo p eepaype 100C 2 oyee opo oppo, aepo Ayaoc papao peapao a ocoe aocoepax oxoo pooca ooa, pox py e oy aoc, oycoea e, o a ocoe ao ece p oepc, xo, % o.

cooex opo oppo aepo.

2.1 Ce peapaa -1 Ce peapaa, oy ycooe aae -1, ocoa a aoec eoa c aoepy aeo, aece oopoo cooa oxo pooca ooa ceyeo cocaa, % acc.:

Tpea 0,01 ea 7,0-18,N, N-epaeeea 8,025,1,3,5-peecapo-1,3,5-pa 0,5-3,Boa 1,0-10,Meao 40,0 - 60,X poecca oye -1 cey:

Ha epo ca pocxo oeca eoa N,Nepaeeeaa c eee eaa. aee peaoy cec oa opa ca eaa.

Cec paopea o 110C, epeeaec ee 1,5 aco. o ooa peaoy cec o 1-2% yaopa O-10.

Pea poeae o ceye cxee:

Ha yeo e eoc poee pea eepayp a coca peaoo cpe.

Bpe pea, Bpe pea, Pc. 4. Be eepayp pea a copoc cepa eoa (a) xo poyo aoepoa: () OM-1, () OM-2, () OM-Teepaypa, C: 1-80C, 2-90C, 3-100C, 4-110C a o pcya 4, c yeee eepayp pocxo yeee copoc opaoa OM-1 (pc 4). oce c yeee pee pea o cyae pea c aoepy aeo c opaoae OM-2 OM-3, coepae oopx a o pc. 4-, , aeo opacae c yeee eepayp. Ta, ec p eepaype 80C coepae OM-3 cocao 3-4 % a a aca pea, o p 120C ex e ycox xo OM-3 opoc o 40-45%.

a oaa cceoa, aoee oa c o pe pyx coc ec cey coca peapaa -1, % acc..

2-eaoeeo - 12-2,6--(eaoeeo) - 17-2,4,6-p-(eaoeeo) - 13-N, N-epaeeea - 5-O-1O - 1-Boa - 20-Peya ca peapaa -1 aece opa cepooopoo oppo peaea oae eeeoc cyaoccaaax aep oaa, o p oepa 75 / oeceaec 100% oaee poca CB cee a o oppo C. 3 ocae 96%.

cceoa oaa, o ey cee a o oppo coepae -1 N, N-epaeeea eec opeeea acoc (c. pc. 5).

Pc. 5. acoc cee a o oppo o coepa ope N, N-epaeeeaa Ta opao, oye peapa -1 oaae po cepo ec (op oppo o oae poca CB).

2.2 peaaea exooeca cxea ya cea "-1" e cea peapaa "-1" cooec c pcyo 6 coco px epo copa cp, peaopa c oaco eao, oapoo I II VII III VII IV V VI VII VII Pc. 6. paa exooeca cxea ya cea "-1" 1 ep copa eoa; 2 ep copa A; 3 ep copa opaa; 4 oapo y; 5 peaop. oo: I eo; II A; III opa; IV peaoa cec; V eao; VI eeo poy ("-1"); VII ap ya c cpoeo peaoo ooo. eo co caa oac ep (1), oopeaec, ae ocyae peaop (5). A c ya aoepoa 2,6--pe-yeoa ex H-13 oac ep (2) aee peaop (5). B peaope oeceaec ecoe ceee ooo, o cococye ooy poea pea. Teo peaop ooc epe cey, oae pyay apa p=6 c/c2. oce ae ae peaope ce 3,5 c/c2, o ceecye o ee xoe pea eaa, peaop (5) ocyecec opoa oaa opaa epa (3). poecc aepaec epe 1,aca. ae peaoa cec ocyae oapo y (4) c e oo eaoa aeeo eo cooa aece pacope. eeo poy opaec a ca.

Pacxoe op cp a 1 oy peapaa "-1": eo 220 ;

A 600 ; opa 180 .

2.3 Ce peapaa -2 Ce peapaa -2 ocyece a ocoe aoec aocoepax oxoo pooca ooa 73% pacopo opoocopo co. Ce ocyecc p eepaype 50-60C eee 40 y accoo coooe opoocopa coa : a pao 1:3,5-4,5. Bxo 96-99%. Coca peaoo cec, opeee eoo aooco xpoaopa, ee cey coca, % acc.:

[(CH3)3NH+]3PO43- - 0,[(CH3)2NH2+]3PO43- - 11,[(CH3)2NH+CH2N(CH3)2]3P043- - 25,(C6H16N3) 3PO43- - 26,Boa - 26,Meao - 35,Opeeee ax coc poo o peyaa ca epoao poao oppooo cpee, oopa oepoaa acoe o Caoopcoo ecopoe pcyc cepooopoa: Cl- - 10667; HCO3 - 470-500; H2S - 80-100; Ca2+ - 2100-2300;

Hg2+ - 36-40 /.

a oaa ca, peapa -2 oeceae 100% oaee poca CB p oepa 150 / a e ocae 97 % p oepa 75 /.

cceoa oaa, o py e peapaa ooe e oaae coooee peaeo (c. pc.7).

Pc. 7. acoc cee a opa o coooe opoocopa coa : a a o pc. 7 oa coooee peaeo ec 1:4. eee oepa opoocopo co eao caaec a pye ee peapaa.

Bo 1 Ocyec ycoepecoa eo oye N,N-e(3,5--pe-y-4-poce)-aa aocoepax oxoo pooca ooa c xoo eeoo poya 96%. Papaoaa exooeca cxea cea N,N-e-(3,5--pe-y-4poce)-aa. Hae e eepaypo-peeo pe (t=90-110 C, =1-2 .) oye N,N-e-(3,5--pe-y-4poce)-aa.

2 Bepe ocyec ce c-N,N-(3,5--pe-y-4poce)-eaa peae epeapoa N,N-e-(3,5-pe-y-4-poce)-aa 1,3,5-peecapo-1,3,5pao. caoeo, o xo eeoo poya aeo yeaec p cooa opx pacopee, acoc, p cooa eaoa xo 96%, a eaa 30%.

3 Ocyec yxca ce S-(3,5--pe-y-4poce)-eoapaaa eoapaaa a c xoo eex poyo 98% a ocoe aocoepax oxoo pooca ooa.

4 caoeo, o 1,3,5-peecapo-1,3,5-pa cocoe oa poc cyaoccaaax aep (Desulfovibrio desulfuricans BKM-1388, Mycobacterium flavum BKMB-356, Aspergillus niger BKMF-1119) p oepa 200 /.

5 Papaoa poecc oye aoppoox peapao "-1" "-2" a ocoe aocoepax oxoo pooca ooa. Beo, o o oecea cee a o oppo C.3 cepooopocoepax epaoax cpeax 97% p oepa 75/, a ae oa poc cyaoccaaax aep p oepa 75 150 / cooeceo.

Ocooe coepae pao oeo ceyx yax:

1. opae B.B., yae H.C. Ocoae Maxa a ocea pcaa oa// Heeepepaoa eex poe epce. III opecc eeaopoeo Pocc:

Tec oao. a. 2001. C.119-121.

2. opae B.B., yae H.C. Byaa opayyo poo ppoaoo cepoo paa// Heeepepaoa eex poe epce. III opecc eeaopoeo Pocc: Tec oao. a. 2001. C.177179.

3. opae B.B., yae H.C. cceoae accooex poecco acopepax// Teop paa accooex poecco xeco exoo: Tec oao. a. 2001. C.54.

4. opae B.B., yae H.C. cooae oxoo eexecx pooc coa ex opo oppo// Ayae poe Boo-ypaco eeaooco po: Tec oao. a. 2001 . C.72-73.

5. opae B.B., yae H.C. Ho aep oae poca cyaoccaaax yeoopoocx aep// Ayae poe Boo-ypaco eeaooco po: Tec oao. a. 2001. - C.73-74.

6. opae B.B.. cooae oxoo pooca ooa aece ex aeo peox cece a ocoe C-3// Tec oao eyapoo oepe V eyapooo coya oox yex, acpao cyeo. M. 2001. C.108-110.

7. opae B.B. Moa acoepx oo a ocoe C-3 APM-15 eoa coa// Tec oao eyapoo oepe V eyapooo coya oox yex, acpao cyeo. M. 2001. C.110-111.

8. yao .X., opae B.B., Cp A.M., yae H.C.

op oppo aep a oopyoa poeccax o epepao e.// apc xec ypa. a. 2001.

.8. 4. C.50-51.

9. yao .X., opae B.B., Cp A.M., yae H.C.

cceoae eoc opa oppo eao a ocoe aocoepax oxoo pooca// apc xec ypa.

a. .8. 5. 2001. C.40-41.

Cocae B.B. opae ocao ea 25.03.2002. Tpa 90 .

aeco ycoo ocyapceoo eoo execoo yepcea

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