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cceoae eoa oeepaypo eea oaao, o oce yae a cyae aoece c oco a cceye a o co o-xec oaae cooecye opa, pee epa opoa, oope peoeyec pe cex o acaoeox cece p cpoece aoox opo.

Coco cooeepaypo eea aa ocoa a cooa aoo aa cocae coo cp p pooce epaa, oyaeoo cooeepayp oo cx pay. oocoa oo cocoa cooa aa cceoao oeee oyocyxx poco ex eao coocaex c poco eea p eepaypo oec.

Tepopaepece cceoa oaa, o poc ex eao p cooeepaypo oec opay oc ( eepaypo epae o 180 o 420 C (a cee ocoo co e)), oaae cyeceo ee pacopoc oe, a coocaee c poco eea poc eao - epacope epp (400650C). ooy cooeepaypa eea ape coo cp ec ocaoo e poecco ya ao, coepax poc ex eao.

paecoo cooa c a ee exoo pooca peoeyeoe oeco aa cocae coo cp e oo pea 5 %.

5.3. Peoea o oopoy cooa oex cox o oe eoc yae oo ex eao cox o aaecoo pooca MO cooec c a, pecae ae 3, coo-eoo co, oee c oepee ac coo, peoeyec cea c oeaoc coo oce oee ae pH c 6,5-8,5 o 10-10,5. Pace oaa, o ocaooe coepae oo ex eao cc p o o 2 o 70 pa ( Mn2+ o 4000 pa). Ta opao, oo a ce ee pH oe ocyo cyeceoe oee eoc peaeoo eoa.

Oepee xpoc co, oe oopoo axoc a ypoe 100000 3/o coep poe oo Cr3+, Fe3+, Ni2+ eaeo oece o Cu2+, Cd2+ Zn2+, epayec o pH 7,5-9,5.

B acoee pe oce oepea yae poca aa oea oa cpacaec oeaocy ccey aaa. oee ooo yae poco ex eao peoeyec e pH ocae o 9,7-10,0, o oece ooe ocaee oo Cr3+, Cu2+, Fe3+, Zn2+ Ni2+ oo pacopoc Cd(OH)2 ye 4 paa e ao pacopoc.

o opa oeoo xpocoo coa ocooe pooco eooe -a oeoo coecoepa o cya-oa. Oao pepo a 50% oe xpoc co oe opae cooa poecce po eae oce aaecx a. Coaco ec epayp a, oe xpoc co peoeyec cooa ae p pooe caoo-oxaax oce.

ooec e o oeo copae ooopee a ce opaa oopooo oocae (60000 3/o) cooecye 456 c py./o.

BBO 1. Ocyece pace pacopoc poco eea (III), xpoa (III), a (II), a (II), oaa (II), e (II), e (II), apaa (II) ca (II) ox pacopax, ocoa a yee cyapx oepa aoa eaa cex eo pocooeco, paccaex poee pacopoc poca eaa, oca poa, ox cyeax oca opaoa oeco ooo poee o.

poeeo coocaee ao pacopoc poco ex eao co ae peeo-oycx oepa () oo eao ooeax. caoeo, o peae eo, ocoa a ocae poco, e oeceae ocee oaaee o ooeo poxoceoo aae o ooy yex poco (poe xpoa). ooeo yypo-ooo xoceoeoo ooooa ocee ae ooo oo poco xpoa, e apaa.

2. oaao, o ae pH, oeceae ay pacopoc poco eao, co oac py o pya axoc epae o 4 o 13, o pe e ooe opoa poecc ocae poco p oopeeo pcyc pax eao pacope. p aex pH 6,5-8,5, papeex cpoca cox o ooe, acao cee oe ocae oo poc eea.

poc eea, xpoa, a e p coeco pcyc oo eao cox oax ooc ocaac oo p pH 9-10, p pH 10,0-10,7 coeco oy ocae poc oaa, a, e, e eea, p pH 11,0-11,5 - poc a, ca, oaa, e eea, p pH 11,2-12,0 ooo coecoe ocaee poco apaa, a, oaa, e eea. coo oopocpoeoo pooceoo oee oee eoc peaeoo eoa oe ocyo a ce ee pH coo-eooo coa c 6,5-8,5 o 10,0-10,5, a xpocoo coa o 9,7-10,0, o cae ocaooe coepae oex ex eao cox oax 2-60 pa.

3. Ha ocoa ax pH-epecoo cceoa aoec coe e, oaa, a, e, xpoa eea c e apo ox pacopax ycaoeo, o ope o cx poco ocaac oo eeo e, ocae ea ocaac ope ocox coe epeeoo cocaa. Cooc coocae poco eao c poco eea oe paea cey po:

Cr>Co>Cu>Zn>Ni. peoe exa coocae poco eao, ocoa a pecaex o poce eea a aoepo oepoe.

4. cceoa ee ooe coca aa oeaocx ocx coopye coo oopocpoeoo pooceoo oee yea oacoc aa opyae cpe. peoe eo oe oeao oacoc ao ox oeo, ocoa a yee coepa eaex p pH=4,8 ex eao aa ae x ooeo, oo pacca oe o, eoxo oeecoo paae aa o eoacoo ypo.

5. Papaoa eo ce oacoc aa opyae cpe, ocoae a yae pacopx op ex eao aa coo coo, a cooa aa cocae acaoeox cece (oeepaypa eea) cocae epaa (cooeepaypa eea).

6. Papaoa peoea o acoy cooa oex cox o pooce caoo-oxaax oce poeccax po aaecx op.

Ocooe coepae ccepa oyoao ceyx paoax:

1. ecpo C.B., pacoopca H.H., Coxa B.., caea O.., aypaoa A.C. oeaa ooeca oacoc ao aaecx pooc ox oeo // eoacoc eeeoc. - 2002. - 2. - C. 18-21.

2. Coxa B.., caea O.., ecpo C.B., pacoopca H.H.

Pace ao pacopoc poco ex eao oe // ypa eco x. - 2002. - T. 76. - 2. - C. 1416-1417.

3. Coxa B.., caea O.., aypaoa A.C., ecpo C.B., pacoopca H.H. Pace pH ocae poco ex eao // apc xec ypa. - 2001. - T. 8. - 4. - C. 24-25.

4. ecpo C.B., Aecapo .B., Coxa B.., aeo A.P., pacoopca H.H. peee peeoaooo aaa p cceoa ooeoo cocaa ao aaecx pooc // apc xec ypa. - 2002. - T. 9. - 1. - C. 49-52.

5. pacoopca H.H., ecpo C.B., Coxa B.. oxec aa peaeoo eoa yae oo ex eao cox o // Bec AT. - 2001. - 2(4). - C. 51-57.

6. pacoopca H.H., ecpo C.B., Coxa B.. epcee exoo ya ao aaecx pooc // Hoe aepa exoo 98.: Te. o. Bcepoccco ay.-ex. o. M.: MATPT . . . oocoo, 1998. - C. 316-317.

7. Coxa B.. Toce ea aax aaecoo pooca MO // eoacoc eeeoc.: Te. o. II Pecyacoo oypca ay. pao cyeo yo P. a: AT, 1998. - C. 11-12.

8. Coxa B.., oe A. B., aea E. B., oeo .H., ecpo C.B., pacoopca H.H. apee opyae cpe eoop poeea // oo opoe e ee Pecye aopoca.: Maepa o. Pecyaco ay.-pa. o.- .II.- a:

c. ay.-cce. c. e pya o. e., 1998. - C.127-129.

9. Coxa B.. Tee ea ae aaecoo pooca // Cye ayo-exec popecc.: Maepa XXXVII Meyapoo ay. cy. o. - Hoocpc: H, 1999. - C. 42- 43.

10. Coxa B.., ecpo C. B., pacoopca H. H. ooece poe ape opyae cpe e eaa // oo, py, opoe. B XXI e.: Maepa Bcepoccco ay.-pa.

o. . II. - a: H MT , 1999. - C. 21-25.

11. Coxa B.., yo .B., ooc B.C., ecpo C.B., pacoopca H.H. o-xecoe oocoae ya ao p pooce epaa // popecca exoo opoc oo aaoexe pooce eax a.: C. aepao Bcepoccco ay.-ex. o. - ea: , 1999. - C. 18-19.

12. Coxa B.., Cpyoe .., Coao B.A., Meee B.E., ecpo C.B., pacoopca H.H. peee ao ocx coopye p cpoece aoox opo // Bope pecypc: coaoooece, ooece exooece ace.: C. aepao Meyapoo ay.-pa. o. - ea: , 1999. - C. 22-23.

13. e O.B., aypaoa A.C., axpcao P.., Coxa B.., ecpo C.B. Oca cox o o ocx coe e, e a // Haya-opaoae-pooco pee ooecx poe.: Maepa o. Meyapoo ay.-ex. o. - a: AT, 1999. - C. 92-94.

14. Coxa B.., Caapoa B. ., ecpo C.B., pacoopca H.H.

Ocoeoc oee poco ex eao aax // oa, oxo pooca opee: poe oxpa opo.: C. aepao Meyapoo ay.-pa. o. - ea: , 1999. - C.113-116.

15. caea O. ., Eeea . ., Coxa B.., ecpo C.B., pacoopca H.H. yee ocae ocx coe oaa xpoa p peaeo oce cox o // Haya-opaoae-pooco pee ooecx poe.: Maepa Meyapoo ay.-ex. o. - a: AT, 1999. - C. 94-95.

16. Coxa B.. Pace acca oacoc aa oeaocx ocx coopye MO // eoacoc eeeoc.: Te. o. III Pecyacoo oypca ayx pao cyeo yo P. - a: AT, 2000. - C. 19-20.

17. Coxa B.., e O. B., ecpo C.B., pacoopca H.H.

cceoa eoc peaeo oc cox o o ocx coe e // popecca exoo opoc oo aaoexe pooce eax a.: C. aepao Bcepoccco o. - ea:

, 2000. - C. 45- 47.

18. Coxa B.. aypaoa A.C., ecpo C.B., pacoopca H.H. Aa yco oc cox o o ocx coe a ye ocae // Xoceo-ea coe o: poe oc cooa.: C. aepao Meyapoo-pa. o. - ea: , 2000. - C. 109-111.

19. Coxa B.., ecpo C.B., pacoopca H.H. Oea eoc oc cox o o ocx coe a peae eoo // Xoceo-ea coe o: poe oc cooa.:

C. aepao Meyapoo-pa. o. - ea: , 2000. - C. 107-108.

20. Coxa B.., axpcao P.., ecpo C.B., pacoopca H.H. O o eoc peaeoo eoa ecoepax cox o // popecca exoo opoc oo aaoexe pooce eax a.: C. aepao Bcepoccco o. - ea: , 2000. - C. 44-45.

21. Coxa B.., Eeea . ., ecpo C.B., pacoopca H.H.

Oa yco ocae poca xpoa (III) p oce cox o // ooeca eoacoc peoo Pocc.: C. aepao epeoaoo ay.-ex. ceapa. - ea: , 2000. - C. 74-76.

22. Coxa B.., caea O. ., ecpo C.B., pacoopca H.H.

Tepoaec aa oc oacoepax cox o peae eoo // ooeca eoacoc peoo Pocc.: C. aepao epeoaoo ay.-ex. ceapa. - ea: , 2000. - C. 80-82.

23. Coxa B.., ecpo C.B., pacoopca H.H. O oooc pee ao oeaocx ocx coopye cpoeo oece // epce pa ecoo cpoeoo oeco, ooo eepx ayx apo a opoe XXI ea.: C. op. aepao Meyapoo ay.-ex. o. - . II. - pc: TA, 2000. - C.

29-30.

24. ecpo C.B., caea O.., Coxa B.., pacoopca H.H.

Oea eoc peaeoo eoa yae oo ex eao cox o aaecx pooc // ae op popocpoe aocpoe.: C. aepao Bcepoccco ay.-pa.

o. - ea: , 2002. - C. 61-63.

25. ecpo C.B., Coxa B.., caea O.., pacoopca H.H.

o-xec aa peaeoo eoa yae oo ex eao cox o // poea oo. Meyapoe caap aeca ISO cep 9001 14000.: Maepa ceap. o. ceapa. - a, 2002. - C. 29-32.

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